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Silver metavanadate | CAS Number: 13497-94-4

Catalog Number
ACM13497944
Product Name
Silver metavanadate
Structure
CAS Number
13497-94-4
Synonyms
SILVER METAVANADATE;SILVER VANADATE;SILVER VANADATE(V);SILVER VANADIUM OXIDE;SILVER ORTHOVANADATE;silvervanadiumoxide(agvo3);Sivermetavanadate;Vanadicacid,silver(1+)salt
Molecular Weight
206.81
Molecular Formula
AgO3V
Purity
98%
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1Acid-Base-Triggered Structural Transformation of a Polyoxometalate Core Inside a Dodecahedrane-like Silver Thiolate Shell.

Liu H1, Song CY1, Huang RW2, Zhang Y1, Xu H2, Li MJ1, Zang SQ3, Gao GG4.

Angew Chem Int Ed Engl. 2016 Mar 7;55(11):3699-703. doi: 10.1002/anie.201511765. Epub 2016 Feb 16.

Self-assembly of metavanadate and organosilver(I) salts leads to a novel dodecahedrane-like [Ag30 ((t) BuS)20 ](10+) silver(I) thiolate nanocage that tightly wraps an unusual C2h polyoxovanadate anion. The polyoxovanadate core undergoes transformation to a D3d configuration upon acidification, and reverts back to its original C2h structure upon addition of base. Chromism was observed for the silver(I) thiolate cluster during the configurational change of the central polyoxovanadate core; the color of the solution changes reversibly from green to dark yellow. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA