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Samarium(iii)iodide | CAS Number: 13813-25-7

Catalog Number
ACM13813257
Product Name
Samarium(iii)iodide
Structure
CAS Number
13813-25-7
Synonyms
Samariumiodide(SmI3);Samariumtriiodide;SAMARIUM(III) IODIDE;SAMARIUM(III) IODIDE, ANHYDROUS, POWDER,99.9+%;SAMARIUM(III) IODIDE ANHYDROUS POWDER;Samarium(III)iodideanhydrous;Samarium(Ⅲ)iodide;Samarium(III) triiodide
Molecular Weight
531.07
Molecular Formula
I3Sm
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1Deciphering a 20-Year-Old Conundrum: The Mechanisms of Reduction by the Water/Amine/SmI2 Mixture.

Maity S1, Hoz S2.

Chemistry. 2015 Dec 7;21(50):18394-400. doi: 10.1002/chem.201503104. Epub 2015 Nov 3.

The reaction of SmI2 with the substrates 3-methyl-2-butanone, benzyl chloride, p-cyanobenzyl chloride, and anthracene were studied in the presence of water and an amine. In all cases, the water content versus rate profile shows a maximum at around 0.2 M H2 O. The rate versus amine content profile shows in all cases, except for benzyl chloride, saturation behavior, which is typical of a change in the identity of the rate-determining step. Read More

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Email:
Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA