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Samarium bromide | CAS Number: 13759-87-0

Catalog Number
ACM13759870
Product Name
Samarium bromide
Structure
CAS Number
13759-87-0
Synonyms
SAMARIUM(III) BROMIDE;SAMARIUM BROMIDE;samariumbromide(smbr3);samarium tribromide;SAMARIUM(III) BROMIDEANHYDROUSBEADS&;Samarium bromide hexahydrate, 99.99%;SAMARIUM BROMIDE, 99.9%;SAMARIUM(III) BROMIDE HEXAHYDRATE: 99.99%
Molecular Weight
390.07
Molecular Formula
Br3Sm
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1Lithium Bromide/Water as Additives in Dearomatizing Samarium-Ketyl (Hetero)Arene Cyclizations.

Rao CN1, Bentz C1, Reissig HU2.

Chemistry. 2015 Nov 2;21(45):15951-4. doi: 10.1002/chem.201502912. Epub 2015 Sep 14.

New conditions for dearomatizing samarium-ketyl (hetero)arene cyclizations are reported. In many examples of these samarium diiodide-mediated reactions, lithium bromide and water can be used as additives instead of the carcinogenic and mutagenic hexamethylphosphoramide (HMPA). The best results were obtained for the cyclizations of N-acylated indole derivatives delivering the expected indolines in good yields and excellent diastereoselectivities. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA