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Home > Product > Precious Metal Catalyst > (S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride

(S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride | CAS Number: 307926-51-8

Catalog Number
ACM307926518
Product Name
(S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
Structure
CAS Number
307926-51-8
MDL Number
MFCD02684548
Synonyms
(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) chloride
Molecular Weight
607.26
Molecular Formula
C36H52AlClN2O2
Melting Point
>350 °C(lit.)
Appearance
yellow powder
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H302-H312-H332
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1Cr(III)(salen)Cl catalyzed asymmetric epoxidations: insight into the catalytic cycle.

Bryliakov KP1, Talsi EP.

Inorg Chem. 2003 Nov 3;42(22):7258-65.

Intermediates of chromium-salen catalyzed alkene epoxidations were studied in situ by EPR, (1)H and (2)H NMR, and UV-vis/NIR spectroscopy (where chromium-salens were (S,S)-(+)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino chromium(III) chloride (1) and racemic N,N'-bis(3,4,5,6-tetra-deuterosalicylidene)-1,2-cyclohexanediamino chromium(III) chloride (2)). High-valence chromium complexes, intermediates of epoxidation reactions, were detected and characterized by EPR and NMR. Read More

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Tel:1-201-478-8534
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