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Home > Product > Precious Metal Catalyst > (S)-Ru(oac)2(h8-binap)

(S)-Ru(oac)2(h8-binap) | CAS Number: 142962-95-6

Catalog Number
ACM142962956
Product Name
(S)-Ru(oac)2(h8-binap)
Structure
CAS Number
142962-95-6
MDL Number
MFCD09753023
Synonyms
Diacetato[(S)-(−)-2,2′-bis(diphenylphosphino)-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-binaphthyl]ruthenium(II)
Molecular Weight
849.89
Molecular Formula
C48H46O4P2Ru
Appearance
pale yellow powder
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H319-H335
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1Practical stereoselective synthesis of (2,3,4, 5-tetrahydro-1H-benzo[b]azepin-5-yl)acetic acid.

Shinohara T1, Kondo K, Ogawa H, Mori T, Nozaki K, Hiyama T.

Chirality. 2000 Jun;12(5-6):425-30.

Highly enantioselective asymmetric hydrogenation of readily accessible olefins, (E)- and (Z)-[1-(toluene-4-sulfonyl)-1,2,3, 4-tetrahydro-1H-benzo[b]azepin-5-ylidene]acetic acid (4a and 4b, respectively) and [1-(toluene-4-sulfonyl)-2, 3-dihydro-1H-benzo[b]azepin-5-yl]acetic acid (4c), is presented as an efficient and straightforward route to (R)-[1-(toluene-4-sulfonyl)-2,3,4, 5-tetrahydro-1H-benzo[b]azepin-5-yl]acetic acid [(R)-1] which is a key intermediate for the synthesis of non-peptide AVP V2-agonist. Read More

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