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Home > Product > Precious Metal Catalyst > (S)-[Rh COD TCFP]BF4

(S)-[Rh COD TCFP]BF4 | CAS Number: 705945-68-2

Catalog Number
ACM705945682
Product Name
(S)-[Rh COD TCFP]BF4
Structure
CAS Number
705945-68-2
MDL Number
MFCD11973806
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;ditert-butyl(methylphosphanylmethyl)phosphane;2-methylpropane;rhodium;tetrafluoroborate
Synonyms
(S)-(-)-t-Butylmethyl(di-t-butylphosphinomethyl)phosphino(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Molecular Weight
560.24
Exact Mass
560.20000
Molecular Formula
C22H44BF4P2Rh
Purity
96%
Appearance
yellow to orange powder
InChIKey
NNPQKTQTQCHMNQ-KJWGIZLLSA-N
H-Bond Donor
0
H-Bond Acceptor
6
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H315-H319-H335
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1Molecular dynamics simulation of the structure and interfacial free energy barriers of mixtures of ionic liquids and divalent salts near a graphene wall.

Gómez-González V1, Docampo-Álvarez B1, Méndez-Morales T1, Cabeza O2, Ivaništšev VB3, Fedorov MV4, Gallego LJ1, Varela LM1.

Phys Chem Chem Phys. 2016 Dec 21;19(1):846-853. doi: 10.1039/c6cp07002g.

A molecular dynamics study of mixtures of 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) with magnesium tetrafluoroborate (Mg[BF4]2) confined between two parallel graphene walls is reported. The structure of the system is analyzed by means of ionic density profiles, lateral structure of the first layer close to the graphene surface and angular orientations of imidazolium cations. Free energy profiles for divalent magnesium cations are calculated using two different methods in order to evaluate the height of the potential barriers near the walls, and the results are compared with those of mixtures of the same ionic liquid and a lithium salt (Li[BF4]). Read More

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA