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Home > Product > Material & Chemicals > Metal & Ceramic Materials > Ruthenium(iii)nitrosylchloride

Ruthenium(iii)nitrosylchloride | CAS Number: 32535-76-5

Catalog Number
ACM32535765
Product Name
Ruthenium(iii)nitrosylchloride
Structure
CAS Number
32535-76-5
Synonyms
RUTHENIUM NITROSO CHLORIDE;RUTHENIUM NITROSYL CHLORIDE;RUTHENIUM(III) NITROSYLCHLORIDE;RUTHENIUM(III) NITROSYL CHLORIDE HYDRATE;RUTHENIUM (III) NITROSYL CHLORIDE MONOHYDRATE
Molecular Weight
237.44
Molecular Formula
Cl3NORu
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1Synthesis, spectroscopic analysis and photolabilization of water-soluble ruthenium(III)-nitrosyl complexes.

Merkle AC1, McQuarters AB, Lehnert N.

Dalton Trans. 2012 Jul 14;41(26):8047-59. doi: 10.1039/c2dt30464c. Epub 2012 Jun 7.

In this paper, the synthesis, structural and spectroscopic characterization of a series of new Ru(III)-nitrosyls of {RuNO}(6) type with the coligand TPA (tris(2-pyridylmethyl)amine) are presented. The complex [Ru(TPA)Cl(2)(NO)]ClO(4) (2) was prepared from the Ru(III) precursor [Ru(TPA)Cl(2)]ClO(4) (1) by simple reaction with NO gas. This led to the surprising displacement of one of the pyridine (py) arms of TPA by NO (instead of the substitution of a chloride anion by NO), as confirmed by X-ray crystallography. Read More

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Tel:1-201-478-8534
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