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Home > Product > Precious Metal Catalyst > Rhodium(III)iodide

Rhodium(III)iodide | CAS Number: 15492-38-3

Catalog Number
ACM15492383
Product Name
Rhodium(III)iodide
Structure
CAS Number
15492-38-3
MDL Number
MFCD00016311
IUPAC Name
rhodium(3+) triiodide
Synonyms
Rhodium(III) triiodide
Molecular Weight
483.62
Exact Mass
483.61900
Molecular Formula
RhI3
Purity
Rh ≥21.3%
Appearance
black crystals
InChIKey
KXAHUXSHRWNTOD-UHFFFAOYSA-K
H-Bond Donor
0
H-Bond Acceptor
3
Symbol
GHS07
Safty Description
S22:Do not breathe dust . S24/25:Avoid contact with skin and eyes .
Hazard Statements
H317-H319
WGK Germany
3
Stability
Stable.
Packing Group
I; II; III
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1Facile synthesis and versatile reactivity of an unusual cyclometalated rhodium(I) pincer complex.

Jongbloed LS1, de Bruin B, Reek JN, Lutz M, van der Vlugt JI.

Chemistry. 2015 May 4;21(19):7297-305. doi: 10.1002/chem.201406463. Epub 2015 Mar 24.

The synthesis of the reactive PN(C(H) ) ligand 2-di(tert-butylphosphanomethyl)-6-phenylpyridine (1(H) ) and its versatile coordination to a Rh(I) center is described. Facile C-H activation occurs in the presence of a (internal) base, thus resulting in the new cyclometalated complex [Rh(I) (CO)(κ(3) -P,N,C-1)] (3), which has been structurally characterized. The resulting tridentate ligand framework was experimentally and computationally shown to display dual-site proton-responsive reactivity, including reversible cyclometalation. Read More

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Tel:1-201-478-8534
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Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA