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Home > Product > Precious Metal Catalyst > Rhodium hydroxide

Rhodium hydroxide | CAS Number: 21656-02-0

Catalog Number
ACM21656020
Product Name
Rhodium hydroxide
Structure
CAS Number
21656-02-0
MDL Number
MFCD00149842
Synonyms
Rhodium trihydroxide
Molecular Weight
153.93
Molecular Formula
Rh(OH)3
Density
g/cm3
Purity
Rh ≥66.0%
Appearance
lemon yellow powder
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1sp3-sp2 vs sp3-sp3 C-C site selectivity in Rh-catalyzed ring opening of benzocyclobutenol: a DFT study.

Ding L1, Ishida N, Murakami M, Morokuma K.

J Am Chem Soc. 2014 Jan 8;136(1):169-78. doi: 10.1021/ja407422q. Epub 2013 Dec 16.

The C(sp(3))-C(sp(2)) vs C(sp(3))-C(sp(3)) site selectivity in the C-C bond activation in Rh-catalyzed ring opening of benzocyclobutenol was systematically investigated using density functional theory (DFT). The catalytic cycle includes three elementary steps: the proton transfer from the substrate to a rhodium hydroxide, the C-C cleavage, and the proton transfer from water onto a carbon forming the final product with regeneration of the rhodium hydroxide. Read More

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Email:
Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA