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Home > Product > Nanomaterials > Metal Nanomaterials > Nanoparticles & Nanopowders > Rhenium Oxide Nanoparticles / Nanopowder

Rhenium Oxide Nanoparticles / Nanopowder | CAS Number: 12036-09-8

Catalog Number
ACM12036098
Product Name
Rhenium Oxide Nanoparticles / Nanopowder
Structure
CAS Number
12036-09-8
MDL Number
MFCD00016305
Synonyms
Rhenium dioxide
Molecular Weight
218.21
Molecular Formula
ReO2
Melting Point
1000 °C (1832 °F)
Density
11.4 g/cm3
Purity
99%, 99.9%, 99.99%, 99.999%
Appearance
Powder
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1Selective electrocatalytic oxidation of a re-methyl complex to methanol by a surface-bound Ru(II) polypyridyl catalyst.

Coggins MK1, Méndez MA, Concepcion JJ, Periana RA, Meyer TJ.

J Am Chem Soc. 2014 Nov 12;136(45):15845-8. doi: 10.1021/ja507979c. Epub 2014 Oct 29.

The complex [Ru(Mebimpy)(4,4'-((HO)2OPCH2)2bpy)(OH2)](2+) surface bound to tin-doped indium oxide mesoporous nanoparticle film electrodes (nanoITO-Ru(II)(OH2)(2+)) is an electrocatalyst for the selective oxidation of methylrhenium trioxide (MTO) to methanol in acidic aqueous solution. Oxidative activation of the catalyst to nanoITO-Ru(IV)(OH)(3+) induces oxidation of MTO. The reaction is first order in MTO with rate saturation observed at [MTO] > 12 mM with a limiting rate constant of k = 25 s(-1). Read More

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Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA