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Rhenium carbonyl | CAS Number: 14285-68-8

Catalog Number
ACM14285688
Product Name
Rhenium carbonyl
Structure
CAS Number
14285-68-8
Synonyms
DECACARBONYLDIRHENIUM;DODECACARBONYLDIRHENIUM;DIRHENIUM DECACARBONYL;RHENIUM CARBONYL;RHENIUM DECACARBONYL;decacarbonyldi-rheniu(thetae-thetae);Re2(CO)10;Rhenium carbonyl (Re2(CO)10)
Molecular Weight
652.52
Molecular Formula
C10O10Re2
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1Synthesis, characterization, and gas-phase fragmentation of rhenium-carbonyl complexes bearing imidazol(in)ium-2-dithiocarboxylate ligands.

Beltrán TF1, Zaragoza G2, Delaude L1.

Dalton Trans. 2016 Nov 15;45(45):18346-18355.

Five complexes with the generic formula [ReBr(CO)3(κ2-S,S'-S2C·NHC)] were obtained by reacting [ReBr(CO)5] with a set of representative imidazol(in)ium-2-dithiocarboxylate zwitterions. These ligands are the adducts of N-heterocyclic carbenes (NHCs) and carbon disulfide. The monometallic Re(i) compounds were further coupled with Na[Re(CO)5] to afford bimetallic Re(0) species. Depending on the experimental conditions, either octacarbonyl dimers [Re2(CO)8(μ2-κ1-S,κ1-S'-S2C·NHC)] or hexacarbonyl clusters [Re2(CO)6(κ2-S,S'-κ3-S,C,S'-S2C·NHC)] were isolated. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA