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Home > Product > Precious Metal Catalyst > (R)-Ru(Oac)2(H8-BINAP)

(R)-Ru(Oac)2(H8-BINAP) | CAS Number: 374067-51-3

Catalog Number
ACM374067513
Product Name
(R)-Ru(Oac)2(H8-BINAP)
Structure
CAS Number
374067-51-3
MDL Number
MFCD09753023
IUPAC Name
acetic acid;[1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane;ruthenium
Synonyms
Diacetato[(R)-2,2′-bis(diphenylphosphino)-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-binaphthyl]ruthenium(II)
Molecular Weight
849.89
Exact Mass
850.19100
Molecular Formula
C48H46O4P2Ru
Purity
96%
Appearance
pale orange powder
SMILES
CC(=O)O.CC(=O)O.C1CCC2=C(C1)C=CC(=C2C3=C(C=CC4=C3CCCC4)P(C5=CC=CC=C5)C6=CC=CC=C6)P(C7=CC=CC=C7)C8=CC=CC=C8.[Ru]
InChIKey
BWYPLACAJUYPKL-UHFFFAOYSA-N
H-Bond Donor
2
H-Bond Acceptor
4
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1Practical stereoselective synthesis of (2,3,4, 5-tetrahydro-1H-benzo[b]azepin-5-yl)acetic acid.

Shinohara T1, Kondo K, Ogawa H, Mori T, Nozaki K, Hiyama T.

Chirality. 2000 Jun;12(5-6):425-30.

Highly enantioselective asymmetric hydrogenation of readily accessible olefins, (E)- and (Z)-[1-(toluene-4-sulfonyl)-1,2,3, 4-tetrahydro-1H-benzo[b]azepin-5-ylidene]acetic acid (4a and 4b, respectively) and [1-(toluene-4-sulfonyl)-2, 3-dihydro-1H-benzo[b]azepin-5-yl]acetic acid (4c), is presented as an efficient and straightforward route to (R)-[1-(toluene-4-sulfonyl)-2,3,4, 5-tetrahydro-1H-benzo[b]azepin-5-yl]acetic acid [(R)-1] which is a key intermediate for the synthesis of non-peptide AVP V2-agonist. Read More

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