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Home > Product > Nanomaterials > Metal Nanomaterials > Nanoparticles & Nanopowders > Pss-chloropropyl-heptaisobutyl substitu&

Pss-chloropropyl-heptaisobutyl substitu& | CAS Number: 480438-84-4

Catalog Number
ACM480438844
Product Name
Pss-chloropropyl-heptaisobutyl substitu&
Structure
CAS Number
480438-84-4
IUPAC Name
Chloropropylisobutyl-PSS
Synonyms
PSS-CHLOROPROPYL-HEPTAISOBUTYL SUBSTITU&;1-CHLOROPROPYL-3,5,7,9,11,-ISOBUTYLPENTA-CYCLO-(9.5.1.1(3,9).)OCTASILOXANE, 97%;pss-chloropropyl-heptaisobutyl substituted;Chloropropylisobutyl-PSS,PSS-Chloropropyl-isobutylsubstituted,1-Chloropropyl-3,5,7,9,11,13,
Molecular Weight
894.015
Exact Mass
892.26300
Molecular Formula
C31H69ClO12Si8
Melting Point
214-219ÂșC(lit.)
Purity
96%
SMILES
CC(C)C[Si]12O[Si]3(O[Si]4(O[Si](O1)(O[Si]5(O[Si](O2)(O[Si](O3)(O[Si](O4)(O5)CC(C)C)CC(C)C)CC(C)C)CC(C)C)CC(C)C)CC(C)C)CCCCl
InChIKey
XVYCGZTZIHTXDL-UHFFFAOYSA-N
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1Coordination of a complete series of N2 reduction intermediates (N2H2, N2H4, and NH3) to an iron phosphine scaffold.

Crossland JL1, Balesdent CG, Tyler DR.

Inorg Chem. 2012 Jan 2;51(1):439-45. doi: 10.1021/ic201873a. Epub 2011 Oct 21.

The series of dinitrogen reduction intermediates (N(2)H(2), N(2)H(4), and NH(3)) coordinated to the Fe(DMeOPrPE)(2)H(+)(DMeOPrPE = 1,2-[bis(dimethoxypropyl)phosphino]ethane) scaffold has been synthesized or generated. The synthesis of trans-[Fe(DMeOPrPE)(2)(NH(3))H][BPh(4)] and generation of trans-[Fe(DMeOPrPE)(2)(N(2)H(4))H][BPh(4)] were achieved by substitu tion of the dinitrogen ligand on trans-[Fe(DMeOPrPE)(2)(N(2))H][BPh(4)]. Read More

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Tel:1-201-478-8534
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