(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP*

• Catalog Number: ACM866081621
• Product Name: (R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP*
• CAS: 866081-62-1
• Category: Heterocyclic Organic Compound
• Synonyms: AK173366; 866081-62-1; (R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline; (R,R)-QuinoxP; (R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline
• IUPAC Name: (R)-tert-butyl-[3-[tert-butyl(methyl)phosphanyl]quinoxalin-2-yl]-methylphosphane
• Molecular Weight: 334.384g/mol
• Molecular Formula: C18H28N2P2
• Canonical SMILES: CC(C)(C)P(C)C1=NC2=CC=CC=C2N=C1P(C)C(C)(C)C
• InChI: InChI=1S/C18H28N2P2/c1-17(2,3)21(7)15-16(22(8)18(4,5)6)20-14-12-10-9-11-13(14)19-15/h9-12H,1-8H3/t21-,22-/m0/s1
• InChI Key: DRZBLHZZDMCPGX-VXKWHMMOSA-N
• Application: Ligand for the rhodium-catalyzed, asymmetric hydrogenation of dehydroamino acid esters and α-enamides.; ; Ligand for the rhodium-catalyzed, asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds.; ; Ligand for the rhodium-catalyzed, asymmetric alkylative ring opening reaction; ; Ligand for the palladium-catalyzed asymmetric allylic alkylation and amination of racemic substrates.; ; Ligand for the ruthenium-catalyzed asymmetric hydrogenation of ketones.; ; Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1,1-disubstituted alkenes with aldehydes.; ; Ligand for the silver-catalyzed asymmetric nitroso aldol reaction.; ; Cu-catalyzed enantioconvergent allyllic borylation.; ; Cu-catalyzed enantioselective cyclopropylation.
• Complexity: 336
• Covalently-Bonded Unit Count: 1
• Defined Atom Stereocenter Count: 2
• Exact Mass: 334.173g/mol
• H-Bond Acceptor: 2
• Heavy Atom Count: 22
• Monoisotopic Mass: 334.173g/mol
• Rotatable Bond Count: 4
• Topological Polar Surface Area: 25.8A^2