Dichloro[(R)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 95%

• Catalog Number: ACM478308917
• Product Name: Dichloro[(R)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 95%
• CAS: 478308-91-7
• Category: Heterocyclic Organic Compound
• Synonyms: 478308-91-7;MFCD06658133;DICHLORO[(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3, 3'-BIPYRIDINE][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II);DiCl[(R)-(+)-2,2',6,6'-tetraMeO-4,4'-bis(diphenylphosphino)-3,3'-bipyr][(1R,2R)-(+)-1,2-diphenylethylenediamine]Ru(II)
• IUPAC Name: dichlororuthenium;(1R,2R)-1,2-diphenylethane-1,2-diamine;[3-(4-diphenylphosphanyl-2,6-dimethoxypyridin-3-yl)-2,6-dimethoxypyridin-4-yl]-diphenylphosphane
• Molecular Weight: 1028.914g/mol
• Molecular Formula: C52H50Cl2N4O4P2Ru
• Canonical SMILES: COC1=NC(=C(C(=C1)P(C2=CC=CC=C2)C3=CC=CC=C3)C4=C(N=C(C=C4P(C5=CC=CC=C5)C6=CC=CC=C6)OC)OC)OC.C1=CC=C(C=C1)C(C(C2=CC=CC=C2)N)N.Cl[Ru]Cl
• InChI: InChI=1S/C38H34N2O4P2.C14H16N2.2ClH.Ru/c1-41-33-25-31(45(27-17-9-5-10-18-27)28-19-11-6-12-20-28)35(37(39-33)43-3)36-32(26-34(42-2)40-38(36)44-4)46(29-21-13-7-14-22-29)30-23-15-8-16-24-30;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h5-26H,1-4H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1
• InChI Key: AKMYBLAYOREDRA-ODQAEMFESA-L
• Application: Effective catalyst for the highly enantioselective hydrogenation of a diverse range of simple aromatic ketones.
• Complexity: 944
• Covalently-Bonded Unit Count: 3
• Defined Atom Stereocenter Count: 2
• Exact Mass: 1028.173g/mol
• H-Bond Acceptor: 8
• H-Bond Donor: 2
• Heavy Atom Count: 65
• Monoisotopic Mass: 1028.173g/mol
• Rotatable Bond Count: 14
• Topological Polar Surface Area: 115A^2

Custom Reviews

January 20, 2023

A highly selective catalyst

Dichloro[(R)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) catalyst for oxidizing 1- olefins to aldehydes using air or oxygen.