Chloronitrosyl[N,N'-bis(3,5-di-tert-butylsalicylidene)-1,1,2,2-tetramethylethylenediaminato]ruthenium(IV)

• Catalog Number: ACM386761713-1
• Product Name: Chloronitrosyl[N,N'-bis(3,5-di-tert-butylsalicylidene)-1,1,2,2-tetramethylethylenediaminato]ruthenium(IV)
• CAS: 386761-71-3
• Category: Heterocyclic Organic Compound
• Synonyms: Chlororuthenium(1+);2,4-ditert-butyl-6-[[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]-2,3-dimethylbutan-2-yl]iminomethyl]phenol;nitroxyl anion
• IUPAC Name: 2,4-ditert-butyl-6-[[3-[(3,5-ditert-butyl-2-oxidophenyl)methylideneamino]-2,3-dimethylbutan-2-yl]iminomethyl]phenolate;nitroxyl anion;ruthenium(4+);chloride
• Molecular Weight: 715.4
• Molecular Formula: C36H56ClN3O3Ru
• Canonical SMILES: CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=NC(C)(C)C(C)(C)N=CC2=C(C(=CC(=C2)C(C)(C)C)C(C)(C)C)O.[N-]=O.Cl[Ru+]
• InChI: InChI=1S/C36H56N2O2.ClH.NO.Ru/c1-31(2,3)25-17-23(29(39)27(19-25)33(7,8)9)21-37-35(13,14)36(15,16)38-22-24-18-26(32(4,5)6)20-28(30(24)40)34(10,11)12;1-2;/h17-22,39-40H,1-16H3;1H;/q;-1;+2/p-1
• InChI Key: JLSGLGOKJIQCOY-UHFFFAOYSA-M
• Storage: Refrigerator
• Complexity: 816
• Covalently-Bonded Unit Count: 4
• Exact Mass: 715.305361
• H-Bond Acceptor: 7
• Heavy Atom Count: 44
• Hydrogen Bond Acceptor Count: 6
• Hydrogen Bond Donor Count: 2
• Monoisotopic Mass: 715.305361
• Rotatable Bond Count: 9
• Topological Polar Surface Area: 83.2 Ų

Custom Reviews

January 20, 2023

Work good in oxidizing reaction

In the catalytic reaction of mixed alcohols, chloronitrosyl[N,N'-bis(3,5-di-tert-butylsalicylidene)-1,1,2,2-tetramethylethylenediaminato]ruthenium(IV) has high selectivity and can selectively catalyze the oxidation of primary alcohols.