(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%

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Catalog Number
ACM250611133
Product Name
(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
Structure
Structure
CAS
250611-13-3
Category
Heterocyclic Organic Compound
IUPAC Name
aluminum;2,4-ditert-butyl-6-[[[(1R,2R)-2-[(3,5-ditert-butyl-6-oxocyclohexa-2,4-dien-1-ylidene)methylamino]cyclohexyl]amino]methylidene]cyclohexa-2,4-dien-1-one;trichloride
Molecular Weight
607.26
Molecular Formula
C36H52AlClN2O2
Canonical SMILES
CC(C)(C)C1=CC(=CNC2CCCCC2NC=C3C=C(C=C(C3=O)C(C)(C)C)C(C)(C)C)C(=O)C(=C1)C(C)(C)C.[Al+3].[Cl-].[Cl-].[Cl-]
InChI Key
QLSHFOGUVHXGGH-ZYOJYBKFSA-K
Melting Point
250-255ºC(lit.)
Application
Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.

Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.

Catalyst used for the asymmetric hydrocyanation of nitroolefins.

Catalyst used in the reaction of epoxides with heterocumulenes.
EC Number
607-518-1
Exact Mass
606.35300
Hazard Statements
Xn: Harmful;
Safety Description
26-36
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