Shivaramaiah R1, Lander L2,3,4, Nagabhushana GP1, Rousse G2,3,4, Tarascon JM2,3,4, Navrotsky A1.
Chemphyschem. 2016 Nov 4;17(21):3365-3368. doi: 10.1002/cphc.201600960. Epub 2016 Sep 23.FeSO4 F-based frameworks have recently emerged as attractive candidates for alkali insertion electrodes. Mainly owing to their rich crystal chemistry, they offer a variety of new host structures with different electrochemical performances and physical properties. In this paper we report the thermodynamic stability of two such K-based "FeSO4 F" host structures based on direct solution calorimetric measurements. Read More