Yuan J1, Zhao W1, Pan M1, Zhu L2.
Macromol Rapid Commun. 2016 Aug;37(15):1282-7. doi: 10.1002/marc.201600206. Epub 2016 May 25.A simple route is reported to synthesize colloidal particle clusters (CPCs) from self-assembly of in situ poly(vinylidene fluoride)/poly(styrene-co-tert-butyl acrylate) [PVDF/P(St-co-tBA)] Janus particles through one-pot seeded emulsion single electron transfer radical polymerization. In the in situ Pickering-like emulsion polymerization, the tBA/St/PVDF feed ratio and polymerization temperature are important for the formation of well-defined CPCs. Read More