Shanthi M1, Mathew CM, Ulaganathan M, Rajendran S.
Spectrochim Acta A Mol Biomol Spectrosc. 2013 May 15;109:105-9. doi: 10.1016/j.saa.2013.02.012. Epub 2013 Feb 21.Poly(vinylidene chloride-co-acrylonitrile) (PVdC-co-AN) based solvent free electrolytes were prepared for different compositions of PVdC-co-AN and LiBF4 using solution casting technique. The ionic conductivity, thermal behavior, complexation and structure of polymer electrolytes have been investigated as a function of LiBF4 content at different weight ratios. DSC studies revealed that the glass transition temperature Tg decreases with the increase of salt concentration up to an optimum level. Read More