Poly(Ethyl Methacrylate)

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Catalog Number
ACM9003423
Product Name
Poly(Ethyl Methacrylate)
CAS
9003-42-3
Category
Polymer/Macromolecule
Description
PEMA is known to exhibit biocompatibility and in vivo stability in its various use in implants and medical devices. Sorption of low solubility gases in PEMA was observed to be comparatively lower that polymers with high transition temperature.
Synonyms
Poly(Ethyl Methacrylate) Mw 515000
IUPAC Name
ethyl 2-methylprop-2-enoate
Molecular Weight
114.14g/mol
Molecular Formula
[C6H10O2]n
Canonical SMILES
CCOC(=O)C(C)=C
InChI
1S/C6H10O2/c1-4-8-6(7)5(2)3/h2,4H2,1,3H3
InChI Key
SUPCQIBBMFXVTL-UHFFFAOYSA-N
Boiling Point
243 °F at 760 mm Hg (NTP, 1992);117.0 °C
Melting Point
-103 °F (NTP, 1992);-75 °C;-103°F
Flash Point
60 °F (NTP, 1992);68 °F (20 °C) (Open cup);20 °C o.c.;60°F
Density
0.9151 at 68 °F (USCG, 1999);0.9135 g/cu cm at 20 °C;Relative density (water = 1): 0.91;0.9151
Solubility
5 to 10 mg/mL at 68° F (NTP, 1992);0.05 M;Slightly soluble in chloroform; miscible with ethanol, ethyl ether;Insoluble in water;In water, 5.4X10+3 mg/L at 25 °C;Solubility in water: poor
Appearance
Powder
Application
Poly(ethyl methacrylate) was used in combination with PVC in preparing new phase-separated polymer electrolyte. It was used to understand the polymer-solvent, polymer-surfactant and solvent-surfactant interaction effects and the intercalation process in nanocomposite preparation method.
Storage
room temp
Alpha Sort
Poly(ethyl methacrylate)
Autoignition Temperature
740 °F (USCG, 1999);393 °C;450 °C
Color/Form
Colorless, liquid
Complexity
105
Covalently-Bonded Unit Count
1
Decomposition
When heated to decomposition, it emits acrid smoke and irritating fumes.
EC Number
202-597-5;618-365-5
Exact Mass
114.06808g/mol
Form
crystalline
Formal Charge
0
Grade
analytical standard
H-Bond Acceptor
2
H-Bond Donor
0
Heat of Vaporization
96 cal/g (4.0X10+5 J/kg; 170 Btu/lb)
Heavy Atom Count
8
ICSC Number
0272
LogP
1.94 (LogP);log Kow = 1.94;1.94
MDL Number
MFCD00084414
Monoisotopic Mass
114.06808g/mol
NSC Number
24152
Odor
Acrid odor
Other Experimental
Conversion factors (wt/vol): 4.66 mg/cu m is equivalent to 1 ppm;Heat capacity: 1.9 J/(g deg K) at 5.0 mm Hg; Heat of polymerization: 57.7 kJ/mol at 5.0 mm Hg;Thermal stability ranking of hazardous organic compounds: rank 204 on a scale of 1 (highest stability) to 320 (lowest stability);Readily polymerized;Henry's Law constant = 5.7X10 atm-cu m/mol at 25 °C (est);Hydroxyl radical reaction rate constant = 2.0X10-11 cu cm/molec-sec at 25 °C (est)
Packaging
25 g in glass bottle
Quality Level
100
Refractive Index
Index of refraction: 1.4147 at 20 °C/D
Rotatable Bond Count
3
RTECS Number
OZ4550000
Transition Temperature
Tg 63 °C
UNII
80F70CLT4O
UN Number
2277;2277;2277;2277
Vapor Density
3.94 (NTP, 1992) (Relative to Air);20.59 (Air = 1);Relative vapor density (air = 1): 3.9;3.94
Vapor Pressure
14 mm Hg at 36 °F ; 26.2 mm Hg at 73° F; 67.0 mm Hg at 118° F (NTP, 1992);20.59 mmHg;20.59 mm Hg at 20 °C;Vapor pressure, kPa at 20 °C: 2;14 mmHg at 36°F, 26.2 mmHg at 73°F, 67 mmHg at 118°F
Viscosity
0.92 mPa (cP)
XLogP3
1.9
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