Zhang S1, Ali S1, Ma H1, Zhang L1, Wu Z1, Wu D1, Hu TS2.
J Phys Chem B. 2016 Nov 3;120(43):11307-11316. Epub 2016 Oct 21.Poly(aryloxy)phosphazenes emerge as an important class of hybrid polymers for a whole range of potential applications. To date, however, little is known about the detailed reaction mechanisms during preparation. This draws a great deal of attention for developing well-defined and well-controllable synthesis methods. In this paper, poly(dichlorophosphazene) (PDCP) has been successfully synthesized, and subsequent reaction with sodium phenoxide or phenol in the presence of K2CO3 can produce poly(bis(phenoxy)phosphazene) (PBPP). Read More