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Phenylmaleic anhydride | CAS Number: 36122-35-7

Catalog Number
ACM36122357
Product Name
Phenylmaleic anhydride
Structure
CAS Number
36122-35-7
Synonyms
3-PHENYL-2,5-DIHYDROFURAN-2,5-DIONE;3-PHENYL-2,5-FURANDIONE;3-PHENYL-FURAN-2,5-DIONE;PHENYLMALEIC ANHYDRIDE;2,5-Furandione, 3-phenyl-;2,5-Furandione,3-phenyl-;Phenylmaleins╬▒ureanhydrid;2-Ph-maleic anhydride radical
Molecular Weight
174.15
Molecular Formula
C10H6O3
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1An Exceptionally Facile Two-Step Structural Isomerization and Detoxication via a Water-Assisted Double Lossen Rearrangement.

Li F1, Huang CH1, Xie LN1, Qu N1, Shao J1, Shao B1, Zhu BZ1,2.

Sci Rep. 2016 Dec 23;6:39207. doi: 10.1038/srep39207.

N-hydroxyphthalimide (NHPI), which is best known as an organocatalyst for efficient C-H activation, has been found to be oxidized by quinoid compounds to its corresponding catalytically active nitroxide-radical. Here, we found that NHPI can be isomerized into isatoic anhydride by an unusually facile two-step method using tetrachloro-1,4-benzoquinone (TCBQ, p-chloranil), accompanied by a two-step hydrolytic dechlorination of highly toxic TCBQ into the much less toxic dihydroxylation product, 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone (chloranilic acid). Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA