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Home > Product > Precious Metal Catalyst > Palladium pivalate

Palladium pivalate | CAS Number: 106224-36-6

Catalog Number
ACM106224366
Product Name
Palladium pivalate
Structure
CAS Number
106224-36-6
MDL Number
MFCD16038138
IUPAC Name
2,2-dimethylpropanoate;palladium(2+)
Synonyms
2,2-Dimethylpropanoic acid palladium(II) salt
Molecular Weight
308.67
Exact Mass
308.02400
Molecular Formula
C10H18O4Pd
Melting Point
230-232 °C
Purity
Pd ≥34.0%
Appearance
yellow powder
SMILES
CC(C)(C)C(=O)[O-].CC(C)(C)C(=O)[O-].[Pd+2]
InChIKey
PAGZTSLSNQZYEV-UHFFFAOYSA-L
H-Bond Donor
0
H-Bond Acceptor
4
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H315-H319-H335
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1C-H bonds as ubiquitous functionality: a general approach to complex arylated pyrazoles via sequential regioselective C-arylation and N-alkylation enabled by SEM-group transposition.

Goikhman R1, Jacques TL, Sames D.

J Am Chem Soc. 2009 Mar 4;131(8):3042-8. doi: 10.1021/ja8096114.

Pyrazoles are important azole heteroarenes frequently found in pharmaceuticals and protein ligands, and there has been a growing interest in new synthetic methods for their preparation. We report the first catalytic intermolecular C-H arylation of pyrazoles, namely SEM-protected pyrazoles and N-alkylpyrazoles, which lays the foundation for a new approach to the synthesis of complex arylated pyrazoles, where new arene rings are directly attached to predetermined positions of the heteroarene nucleus ("topologically obvious synthesis"). Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA