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Palladium(ii)sulfide | CAS Number: 12125-22-3

Catalog Number
ACM12125223
Product Name
Palladium(ii)sulfide
Structure
CAS Number
12125-22-3
EC Number
235-190-6
IUPAC Name
sulfanylidenepalladium
Synonyms
PALLADIUM SULFIDE;PALLADIUM(II) SULFIDE;palladium monosulphide;PALLADIUM(II) SULFIDE, 99.9%;Palladous sulfide;Palladium(II) sulfide, 99% (metals basis), Pd 72% min;Einecs 235-190-6;Palladium sulfide (pds)
Molecular Weight
138.49
Exact Mass
137.87600
Molecular Formula
PdS
Melting Point
950ÂșC
Purity
96%
SMILES
S=[Pd]
InChIKey
NRUVOKMCGYWODZ-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
Safty Description
26-36
Hazard Statements
Xi: Irritant;
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1Palladium-Catalyzed Synthesis of Aryl Vinyl Sulfides via 1,3-Oxathiolanes As Vinyl Sulfide Surrogates.

Schmink JR1, Dockrey SA1, Zhang T1, Chebet N1, van Venrooy A1, Sexton M1, Lew SI1, Chou S1, Okazaki A1.

Org Lett. 2016 Dec 16;18(24):6360-6363. Epub 2016 Dec 1.

A nontraditional approach to synthesizing aryl vinyl sulfides is described. 2,2-Diphenyl-1,3-oxathiolane slowly liberates a vinyl sulfide anion under basic conditions. Using a Pd/Xantphos catalyst system to activate a wide range of aryl bromides, this transient sulfide species can be effectively trapped and fed into a traditional Pd0/PdII catalytic cycle. Scope and limitations of the methodology are presented along with significant discussion of a competitive C-S bond activation by this catalyst system.

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA