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Palladium(ii)oxide | CAS Number: 64109-12-2

Catalog Number
ACM64109122
Product Name
Palladium(ii)oxide
Structure
CAS Number
64109-12-2
Synonyms
PALLADIUM OXIDE;PALLADIUM(+2)OXIDE;PALLADIUM(II) OXIDE HYDRATE;Palladium(II) oxide monohydrate;Palladium(II) oxide hydrate, 99.9+%;PALLADIUM (II) OXIDE, 99.9% (METALS BASIS), PD 75.3% MIN;Palladium(II) oxide monohydrate, 99.9% (metals basis), Pd 73% min;P
Molecular Weight
122.42
Molecular Formula
OPd
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1Application of Pd-Catalyzed Cross-Coupling Reactions in the Synthesis of 5,5-Dimethyl-5,6-dihydro-4H-pyrrolo[1,2-b]pyrazoles that Inhibit ALK5 Kinase.

Tenora L1, Galeta J1, Řezníčková E2, Kryštof V2, Potáček M1.

J Org Chem. 2016 Dec 2;81(23):11841-11856. Epub 2016 Nov 10.

C-H activation of position 3 of a substituted pyrazole ring catalyzed by palladium(II) was straightforward and convenient for arylated or heteroarylated 5,5-dimethyl-5,6-dihydro-4H-pyrrolo[1,2-b]pyrazoles. Moreover, we introduced simple protection of the nitrogen in the pyridin-2-yl directing group, which otherwise does not allow a cross-coupling reaction, by transformation to the N-oxide. Selected final products were reasonably selective ALK5 kinase inhibitors.

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA