Catalog Number
ACM7647101-3
Product Name
Palladium(II) chloride
Category
Metal & Ceramic Materials
Description
Palladium(II) chloride, also known as palladium dichloride and palladous chloride, are the chemical compounds with the formula PdCl2. PdCl2 is a common starting material in palladium chemistry – palladium-based catalysts are of particular value in organic synthesis. It is prepared by chlorination of palladium.
Synonyms
Palladium chloride (PdCl2);dichloropalladium;Palladium(II) Chloride;
IUPAC Name
dichloropalladium;
Canonical SMILES
Cl[Pd]Cl;
InChI
InChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2;
InChI Key
PIBWKRNGBLPSSY-UHFFFAOYSA-L;
Solubility
Soluble (NTP, 1992);Sol in water, ethanol, acetone;Readily soluble in hydrochloric acid and solutions of alkali metal chlorides;
Appearance
Dark brown powder
Application
C-H Activation; Carbonylation; Cross Coupling Reactions with Arenes→Mizoroki Heck Coupling Reaction; Oxidation;
Storage
Store below +30°C.
Covalently-Bonded Unit Count
1
Decomposition
When heated to decomposition it emits highly toxic fumes of /hydrogen chloride/.;Decomposed at high temperature to palladium and chlorine.;
Monoisotopic Mass
175.841g/mol
Other Experimental
DELIQUESCENT; DECOMPOSES @ 500 DEG C;Decomposition at high temperatures to palladium and chlorine;Sublimes at 590 deg C; decomposition begins at 600 deg C and is complete at 740 deg C;Dark brown crystals; soluble in water, alcohol, acetone; reduced in solution by hydrogen or carbon monoxide to metal /Palladium(II) chloride dihydrate/;
Physical Description
PALLADIUM CHLORIDE is a dark brown crystals. (NTP, 1992);
Stability
Stable. Incompatible with strong oxidizing agents.
Storage Conditions
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Topological Polar Surface Area
0A^2
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