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Home > Product > Material & Chemicals > Metal & Ceramic Materials > Nitrosonium hexafluoroantimonate

Nitrosonium hexafluoroantimonate | CAS Number: 16941-06-3

Catalog Number
ACM16941063
Product Name
Nitrosonium hexafluoroantimonate
Structure
CAS Number
16941-06-3
Synonyms
NITROSONIUM HEXAFLUOROANTIMONATE;NITROSONIUM HEXAFLUOROANTIMONATE (V);NITROSONIUM (NITROSYL) HEXAFLUOROANTIMONATE;NITROSYL HEXAFLUORANTIMONATE;NITROSYLHEXAFLUOROANTIMONATE;NITROSONIUM HEXAFLUOROANTIMONATE, 99.9%;Nitrosoniumhexafluoroantimonate,min.97%;Nit
Molecular Weight
265.76
Molecular Formula
F6NOSb
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1Solid-state characterization and photoinduced intramolecular electron transfer in a nanoconfined octacationic homo[2]catenane.

Barnes JC1, Frasconi M, Young RM, Khdary NH, Liu WG, Dyar SM, McGonigal PR, Gibbs-Hall IC, Diercks CS, Sarjeant AA, Stern CL, Goddard WA 3rd, Wasielewski MR, Stoddart JF.

J Am Chem Soc. 2014 Jul 30;136(30):10569-72. doi: 10.1021/ja505093d. Epub 2014 Jul 21.

An octacationic homo[2]catenane comprised of two mechanically interlocked cyclobis(paraquat-p-phenylene) rings has been obtained from the oxidation of the septacationic monoradical with nitrosonium hexafluoroantimonate. The nanoconfinement of normally repulsive bipyridinium units results in the enforced π-overlap of eight positively charged pyridinium rings in a volume of <1.25 nm(3). In the solid state, the torsional angles around the C-C bonds between the four pairs of pyridinium rings range between 16 and 30°, while the π-π stacking distances between the bipyridinium units are extended for the inside pair and contracted for the pairs on the outside--a consequence of Coulombic repulsion between the inner bipyridinium subunits. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA