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Home > Product > Material & Chemicals > Metal & Ceramic Materials > Niobium trichloride 1,2-dimethoxyethane complex

Niobium trichloride 1,2-dimethoxyethane complex | CAS Number: 110615-13-9

Catalog Number
ACM110615139
Product Name
Niobium trichloride 1,2-dimethoxyethane complex
Structure
CAS Number
110615-13-9
IUPAC Name
1,2-dimethoxyethane;niobium(3+);trichloride
Synonyms
NIOBIUM(III) CHLORIDE 1,2-DIMETHOXYETHANE COMPLEX;NIOBIUM(III) CHLORIDE-ETHYLENE GLYCOL DIMETHYL ETHER COMPLEX;NIOBIUM TRICHLORIDE 1,2-DIMETHOXYETHANE COMPLEX;TRICHLORO(1,2-DIMETHOXYETHANE)NIOBIUM;niobium(iii) chloride ethylene glycol dimethyl et;Niobium(
Molecular Weight
289.39
Exact Mass
287.88100
Molecular Formula
C4H10Cl3NbO2
Boiling Point
84.5ºC at 760 mmHg
Melting Point
230ºC (dec.)(lit.)
Flash Point
0ºC
Purity
96%
InChIKey
SBSZUBUHOUKQMN-UHFFFAOYSA-K
H-Bond Donor
0
H-Bond Acceptor
5
Safty Description
26-36/37/39-45
Hazard Statements
C: Corrosive;
Packing Group
III
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1Highly active, thermally stable, ethylene-polymerisation pre-catalysts based on niobium/tantalum-imine systems.

Redshaw C1, Walton M, Clowes L, Hughes DL, Fuller AM, Chao Y, Walton A, Sumerin V, Elo P, Soshnikov I, Zhao W, Sun WH.

Chemistry. 2013 Jul 1;19(27):8884-99. doi: 10.1002/chem.201300453. Epub 2013 May 16.

The reactions of MCl5 or MOCl3 with imidazole-based pro-ligand L(1)H, 3,5-tBu2-2-OH-C6H2-(4,5-Ph2-1H-)imidazole, or oxazole-based ligand L(2)H, 3,5-tBu2-2-OH-C6H2 (1H-phenanthro[9,10-d])oxazole, following work-up, afforded octahedral complexes [MX(L(1,2))], where MX=NbCl4 (L(1), 1a; L(2), 2a), [NbOCl2(NCMe)] (L(1), 1b; L(2), 2b), TaCl4 (L(1), 1c; L(2), 2c), or [TaOCl2(NCMe)] (L(1), 1d). The treatment of α-diimine ligand L(3), (2,6-iPr2C6H3N=CH)2, with [MCl4(thf)2] (M=Nb, Ta) afforded [MCl4(L(3))] (M=Nb, 3a; Ta, 3b). Read More

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