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N-[(Trimethylsilyl)methyl]benzylamine | CAS Number: 53215-95-5

Catalog Number
ACM53215955
Product Name
N-[(Trimethylsilyl)methyl]benzylamine
Structure
CAS Number
53215-95-5
IUPAC Name
1-phenyl-N-(trimethylsilylmethyl)methanamine
Synonyms
1-phenyl-N-(trimethylsilylmethyl)methanamine; N-(Trimethylsilylmethyl)benzyamine; N-[(Trimethylsilyl)Methyl]Benzylamine;
Category
Fluorinated Building Blocks
Molecular Weight
193.36
Exact Mass
193.12900
Molecular Formula
C12H13FO2
Boiling Point
89-90ºC (5 mmHg)
Flash Point
205
Density
0.88
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)(C)CNCC1=CC=CC=C1
InChIKey
WECLUYCAWLJMKM-UHFFFAOYSA-N
Symbol
GHS07
Safty Description
S26-S37/39
Hazard Statements
H302
WGK Germany
3
RIDADR
NONH for all modes of transport
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1Beta-diketiminato calcium and magnesium amides; model complexes for hydroamination catalysis.

Barrett AG1, Casely IJ, Crimmin MR, Hill MS, Lachs JR, Mahon MF, Procopiou PA.

Inorg Chem. 2009 May 18;48(10):4445-53. doi: 10.1021/ic900091x.

In a study relevant to group 2-mediated hydroamination catalysis, the reaction of the beta-diketiminato magnesium alkyl complex [{ArNC(Me)CHC(Me)NAr}Mg((n/s)Bu)] (Ar = 2,6-(i)Pr(2)C(6)H(3)) with benzylamine, 2-methoxyethylamine, pyrrolidine, and 2-methyl-4,4-diphenylpyrrolidine has been shown to yield the corresponding magnesium amide complexes [{ArNC(Me)CHC(Me)NAr}Mg(NR(1)R(2))] (R(1) = H, R(2) = CH(2)Ph, CH(2)CH(2)OMe; R(1) = R(2) = -(CH(2))(4)-, -CH(Me)CH(2)CPh(2)CH(2)-) within the first point of analysis (30 min) at room temperature in near quantitative yield as monitored by (1)H NMR spectroscopy. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA