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Home > Product > Material & Chemicals > Micro/NanoElectronics > Manganese pentacarbonyl bromide

Manganese pentacarbonyl bromide | CAS Number: 14516-54-2

Catalog Number
ACM14516542
Product Name
Manganese pentacarbonyl bromide
Structure
CAS Number
14516-54-2
Synonyms
Manganese, bromopentacarbonyl-, (OC-6-22)-;Mn(CO)5Br;PENTACARBONYLMANGANESE BROMIDE;MANGANESE PENTACARBONYL BROMIDE;BROMOPENTACARBONYLMANGANESE;1-BROMO-2 3 5 6-TETRAFLUORO-4-(TRIFLUOR&;MANGANESE PENTACARBONYL BROMIDE MIN. 98%;Manganesepentacarbonylbromide
Molecular Weight
274.89
Molecular Formula
C5BrMnO5
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1A mild synthesis of unsymmetrical bisalkoxysilanes through catalyzed alcoholysis of hydridosilanes containing C-C multiple bonds and aryl halides.

Scott CN1, Wilcox CS.

J Org Chem. 2010 Jan 1;75(1):253-6. doi: 10.1021/jo9022765.

The synthesis of unsymmetrical bisalkoxysilanes containing unsaturated C-C bonds and alkyl and aryl bromides has been developed. This method is a modification of our previously reported two-step procedure that utilizes readily available catalysts (rhodium acetate dimer and manganese pentacarbonyl bromide) under mild neutral aprotic conditions. Good to moderate yields of the products were obtained in a short period. In this two-step synthesis, unsymmetrical bisalkoxysilanes with groups that can be further functionalized can be prepared effectively without the need to isolate the intermediates.

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA