Liu H1, Tian Z, Wang L, Wang Y1, Li D1, Ma H, Xu R.
Inorg Chem. 2016 Feb 15;55(4):1809-15. doi: 10.1021/acs.inorgchem.5b02700. Epub 2016 Jan 28.An SOD-type metalloaluminophosphate molecular sieve (denoted as SOD-Mn) was ionothermally synthesized by introducing manganese(II) cations into the reaction mixture via MnO-acid or MnO2-reductant reactions. Composition and structure analyses results show that two kinds of manganese(II) cations exist in the SOD-Mn structure. Part of the manganese(II) cations isomorphously substitute the framework aluminum(III) with a substitution degree of ∼30%. Read More