Cosquer G1, Pointillart F, Le Gal Y, Golhen S, Cador O, Ouahab L.
Dalton Trans. 2009 May 14;(18):3495-502. doi: 10.1039/b815865g. Epub 2009 Mar 20.The tetrathiafulvalene based 2-immino-pyrazine derivative (TTF-CHN-2-pyz) () was synthesized and characterized. Its radical cation salt ( (+)PF(6)(-)) was prepared as single crystals by electrocrystallisation. (+)PF(6)(-) crystallizes in the triclinic P1 space group. Four 1 : 2 bis(hexafluoroacetylacetonate)M(ii) complexes coordinated with were prepared (M = Mn for , M = Co for , M = Cu for and M = Zn for ). Read More