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Manganese(ii)bromide | CAS Number: 13446-03-2

Catalog Number
ACM13446032
Product Name
Manganese(ii)bromide
Structure
CAS Number
13446-03-2
Molecular Weight
214.746049
Molecular Formula
Br2Mn
Purity
98%
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1Manganese-Catalyzed Borylation of Unactivated Alkyl Chlorides.

Atack TC1, Cook SP1.

J Am Chem Soc. 2016 May 18;138(19):6139-42. doi: 10.1021/jacs.6b03157. Epub 2016 May 9.

The use of low-cost manganese(II) bromide (MnBr2) and tetramethylethylenediamine (TMEDA) catalyzes the cross coupling of (bis)pinacolatodiboron with a wide range of alkyl halides, demonstrating the first manganese-catalyzed coupling with alkyl electrophiles. This method allows access to primary, secondary, and tertiary boronic esters from the parent chlorides, which were previously inaccessible as coupling partners. Read More

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA