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Lithium thiophenoxide | CAS Number: 2973-86-6

Catalog Number
ACM2973866
Product Name
Lithium thiophenoxide
Structure
CAS Number
2973-86-6
IUPAC Name
lithium;benzenethiolate
Synonyms
LITHIUM THIOPHENOXIDE;Lithium thiophenolate solution;thiophenol lithium salt solution;THIOPHENOL LITHIUM SALT SOLUTION, ~1 M I N THF;LITHIUM THIOPHENOXIDE, 1.0M SOLUTION IN TETRAHYDROFURAN;thiophenol lithium salt;Lithium thiophenolate, 0.6M solution in TH
Molecular Weight
116.11
Exact Mass
116.02700
Molecular Formula
C6H5LiS
Boiling Point
67ºC
Flash Point
1 °F
Density
0.934 g/mL at 25ºC
Purity
96%
SMILES
[Li+].C1=CC=C(C=C1)[S-]
InChIKey
HPFQTCRYSOTMDJ-UHFFFAOYSA-M
H-Bond Donor
0
H-Bond Acceptor
1
Safty Description
16-26-29-33-36/37/39-45
Hazard Statements
F,C
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1Synthesis of macrocyclic precursors of phomactins using [2,3]-Wittig rearrangements.

McGowan G1, Thomas EJ.

Org Biomol Chem. 2009 Jun 21;7(12):2576-90. doi: 10.1039/b903256h. Epub 2009 Apr 27.

The combination of a [2,3]-Wittig rearrangement of a suitably substituted cyclohexenylmethyl propargyl ether with a subsequent conversion of the alkyne to a trisubstituted alkene and cyclisation via intramolecular sulfone alkylation has proved to be a useful stereoselective approach to advanced macrocyclic intermediates for a projected synthesis of phomactins. Thus Luche reduction of methyl (1RS,6SR)-2-(bromomethyl)-1,6-dimethyl-4-oxocyclohex-2-ene-1-carboxylate 24 gave methyl (1RS,4RS,6SR)-2-bromomethyl-4-hydroxy-1,6-dimethylcyclohex-2-ene-1-carboxylate 26 which was protected as its (2-trimethylsilylethoxy)methyl ether 27. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA