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Home > Product > Material & Chemicals > Renewable & Alternative Energy > Lithium[2h4]tetrahydroborate(1-)

Lithium[2h4]tetrahydroborate(1-) | CAS Number: 15246-28-3

Catalog Number
ACM15246283
Product Name
Lithium[2h4]tetrahydroborate(1-)
Structure
CAS Number
15246-28-3
Synonyms
lithium [2H4]tetrahydroborate(1-);Lithium borodeuteride-d4;Lithiumborohydride-d4;LithiuM borodeuteride >=95%
Molecular Formula
BD4.Li
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1[{Me(4)C(2)(C(5)H(4))(2)}Zr(BH(4))(2)], a bis(tetrahydroborate) complex of a bridged zirconocene.

Schaper F1, Brintzinger HH.

Acta Crystallogr C. 2000 Mar 15;56(Pt 3):E78. Epub 2000 Mar 15.

Bis(tetrahydroborato)[1,1,2,2-tetramethyl-1,2-ethylenebis(eta(5)-cyclopentadienyl)]zirconium, (I), was synthesized by the reaction of the zirconocene dichloride with lithium tetrahydroborate. Crystals suitable for X-ray structure analysis were obtained by recrystallization from toluene. The molecule adopts an appproximate C(2v) symmetry. Both tetrahydroborate ligands are eta(2)-coordinated and tilted by 18-19 degrees out of the equatorial plane; the angle B1-Zr1-B2 is 104.7 degrees. The cyclopentadienyl rings show a normal eta(5)-coordinaton, with a centroid-Zr-centroid angle of 124.3 degrees.

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA