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Iron phthalocyanine | CAS Number: 132-16-1

Catalog Number
ACM132161
Product Name
Iron phthalocyanine
Structure
CAS Number
132-16-1
IUPAC Name
Iron phthalocyanine
Synonyms
PHTHALOCYANINE IRON;PHTHALOCYANINE IRON(II) SALT;PHTHALOCYANINE, FERRIC;[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-,(SP-4-1)-Iron;31h-phthalocyaninato(2-)-n29,n39,n31,n32]-[29(sp-4-1)-iro;Iron, [29H,31H-phthalocyaninato(2-)-N(29)-,N(30)-,N(31)-,N(32)-
Molecular Weight
568.37
Exact Mass
568.08500
Molecular Formula
C32H16FeN8
Purity
>95.0%(T)
Appearance
Dark purple-brown powder.
Safty Description
S24/25
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1Iron-Catalyzed Oxidative C-C and N-N Coupling of Diarylamines and Synthesis of Spiroacridines.

Fritsche RF1, Theumer G1, Kataeva O2, Knölker HJ1.

Angew Chem Int Ed Engl. 2016 Dec 5. doi: 10.1002/anie.201610168. [Epub ahead of print]

We describe iron-catalyzed intermolecular oxidative coupling reactions of diarylamines to form substituted 2,2'-bis(arylamino)biaryl compounds, tetraarylhydrazines, and 5,6-dihydrobenzo[c]cinnolines with the same hexadecafluorinated iron-phthalocyanine catalyst. The mild formation of C-C or N-N bonds was controlled by the use of acidic or basic additives. In contrast to most iron-catalyzed dehydrogenative coupling reactions, ambient air could be used as the sole oxidant. Read More

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA