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Home > Product > Material & Chemicals > Organic & Printed Electronics > Iron(iii)phthalocyanine chloride

Iron(iii)phthalocyanine chloride | CAS Number: 14285-56-4

Catalog Number
ACM14285564
Product Name
Iron(iii)phthalocyanine chloride
Structure
CAS Number
14285-56-4
Synonyms
PHTHALOCYANINE IRON(III) MONOCHLORIDE SALT;CHLORO(PHTHALOCYANINATO)IRON(III);IRON(III) PHTHALOCYANINE CHLORIDE;chloro[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]iron;Chloro(phthalocyaninato)iron(Ⅲ);iron(II) phthalocyanine chloride;[FeCl(C32H16N8)];Iron(
Molecular Weight
603.82
Molecular Formula
C32H16ClFeN8
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1A highly efficient biomimetic aromatization of Hantzsch-1,4-dihydropyridines with t-butylhydroperoxide, catalysed by iron(III) phthalocyanine chloride.

Filipan-Litvić M1, Litvić M, Vinković V.

Bioorg Med Chem. 2008 Oct 15;16(20):9276-82. doi: 10.1016/j.bmc.2008.09.004. Epub 2008 Sep 5.

Rapid aromatization of Hantzsch-1,4-DHPs with t-butylhydroperoxide catalysed by iron(III) phthalocyanine chloride is described. The reaction proceeds smoothly at room temperature within 1-35 min and the products of high purity were isolated in excellent yields. To explain the reactivity of this catalytical system plausible mechanism have been proposed to involve formation of high-valent oxoferryl species as in cytochrome P450 itself.

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Tel:1-201-478-8534
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