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Home > Product > Material & Chemicals > Micro/NanoElectronics > Iridium i pentanedionate-cyclo-octadiene complex

Iridium i pentanedionate-cyclo-octadiene complex | CAS Number: 12154-84-6

Catalog Number
ACM12154846
Product Name
Iridium i pentanedionate-cyclo-octadiene complex
Structure
CAS Number
12154-84-6
MDL Number
MFCD08273779
IUPAC Name
cyclooctane; (Z)-4-hydroxypent-3-en-2-one; iridium
Synonyms
1,5-CYCLOOCTADIENE(ACETYLACETONATO)IRIDIUM (I);(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)IRIDIUM(I);IRIDIUM I PENTANEDIONATE-CYCLO-OCTADIENE COMPLEX;((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-o,o’)-iridiu;(1,5-cyclooctadiene)(2,4-pentanedionato)irid
Molecular Weight
383.51
Exact Mass
384.10700
Molecular Formula
C13H19IrO 4*
Boiling Point
152ºC at 760 mmHg
Melting Point
145-150ºC (dec.)
Flash Point
30ºC
Purity
0.98
Appearance
yellow powder
SMILES
C[C-]=CC(=O)C.C1C[CH][CH]CC[CH][CH]1.[Ir]
InChIKey
RBTXDZDKTGRPBP-LWFKIUJUSA-N
H-Bond Donor
1
H-Bond Acceptor
2
Symbol
GHS07
Safty Description
26
Hazard Statements
Xi: Irritant;
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1Efficient Synthesis of Tris-Heteroleptic Iridium(III) Complexes Based on the Zn2+-Promoted Degradation of Tris-Cyclometalated Iridium(III) Complexes and Their Photophysical Properties.

Tamura Y1, Hisamatsu Y1, Kumar S1, Itoh T1, Sato K1, Kuroda R1, Aoki S1.

Inorg Chem. 2016 Dec 30. doi: 10.1021/acs.inorgchem.6b02270. [Epub ahead of print]

We report on the efficient synthesis of tris-heteroleptic iridium (Ir) complexes based on the degradation of tris-cyclometalated Ir complexes (IrL3, L: cyclometalating ligand) in the presence of Brønsted and Lewis acids such as HCl (in 1,4-dioxane), AlCl3, TMSCl, and ZnX2 (X = Br or Cl), which affords the corresponding halogen-bridged Ir dimers (μ-complexes). Tris-cyclometalated Ir complexes containing electron-withdrawing groups such as fluorine, nitro, or CF3 moieties on the ligands were less reactive. Read More

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Tel:1-201-478-8534
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