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Iodine pentoxide | CAS Number: 12029-98-0

Catalog Number
ACM12029980
Product Name
Iodine pentoxide
Structure
CAS Number
12029-98-0
EC Number
234-740-2
IUPAC Name
iodyl iodate
Synonyms
iodineoxide(i2o5);IODINE(V) OXIDE;IODINE PENTOXIDE;IODINE PENTAOXIDE;IODINE OXIDE;IODIC ANHYDRIDE;IODIC ACID ANHYDRIDE;IODOPENTOXIDE
Molecular Weight
333.8
Exact Mass
333.78400
Molecular Formula
I2O5
Melting Point
300-350ÂșC (dec.)
Density
5
Purity
Reagent
Appearance
needle shaped crystals
SMILES
O=I(=O)OI(=O)=O
InChIKey
BIZCJSDBWZTASZ-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
5
Safty Description
S17-S26-S36/37/39-S45
Hazard Statements
O:Oxidizingagent;C:Corrosive;
WGK Germany
3
Stability
Stability Strong oxidizer - contact with combustible material may cause fire. Light and moisture sensitive. Incompatible with organic materials, combustible materials, water.
Packing Group
II
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1A free-radical cascade trifluoromethylation/cyclization of N-arylmethacrylamides and enynes with sodium trifluoromethanesulfinate and iodine pentoxide.

Zhang L1, Li Z, Liu ZQ.

Org Lett. 2014 Jul 18;16(14):3688-91. doi: 10.1021/ol5014747. Epub 2014 Jul 1.

An I(2)O(5)-promoted free-radical cascade trifluoromethylation/cyclization of a broad range of N-arylmethacrylamides and enynes with sodium trifluoromethanesulfinate in aqueous medium has been achieved. This strategy allows highly selective access to a variety of CF(3)-containing oxindoles and pyrrolidines. Electron spin resonance (ESR) studies indicate that atom-transfer processes are involved in this system.

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA