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Hexamethyldisilane | CAS Number: 1450-14-2

Catalog Number
ACM1450142
Product Name
Hexamethyldisilane
Structure
CAS Number
1450-14-2
Synonyms
HEXAMETHYLDISILANE;HMD;DISILANE M6;(CH3)6Si2;1,1,1,2,2,2-Hexamethyldisilane;CH7280;disilane,hexamethyl-;Hecamethyldisilane
Molecular Weight
146.38
Molecular Formula
C6H18Si2
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1Palladium-catalyzed direct intermolecular silylation of remote unactivated C(sp3)-H bonds.

Pan JL1, Li QZ, Zhang TY, Hou SH, Kang JC, Zhang SY.

Chem Commun (Camb). 2016 Nov 18;52(89):13151-13154. Epub 2016 Oct 20.

An efficient and convenient method has been developed to achieve direct silylation of unactivated remote primary or secondary C(sp3)-H bonds to form C-Si bonds with hexamethyldisilane (HMDS). This method highlights the emerging strategy to transform unactivated methyl or methylene into versatile functional groups in organic synthesis and provides a new method to construct functionalized C-Si bonds for synthetic chemistry.

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA