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Home > Product > Material & Chemicals > Micro/NanoElectronics > Hexafluoroantimonic acid

Hexafluoroantimonic acid | CAS Number: 16950-06-4

Catalog Number
ACM16950064
Product Name
Hexafluoroantimonic acid
Structure
CAS Number
16950-06-4
Synonyms
hydrogen,(oc-6-11)-antimonate(1-hexafluoro-;HYDROGEN HEXAFLUOROANTIMONATE(V);HEXAFLUOROANTIMONIC ACID;FLUOROANTIMONIC ACID;hexafluoroantimonyic acid;FLUOROANTIMONIC ACID, TRIPLE-DISTILLED;Hexafluoroantimonicacid6H2O;Hydrogenhexafluoroantimonate(V),65-70%a
Molecular Weight
236.76
Molecular Formula
F6HSb
Purity
65% solution
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1First evidence for the existence of hexafluoroantimonic(v) acid.

Bour C1, Guillot R, Gandon V.

Chemistry. 2015 Apr 13;21(16):6066-9. doi: 10.1002/chem.201500334. Epub 2015 Mar 9.

By reacting IPr⋅InBr3 with AgSbF6 in dichloroethane at room temperature, we could obtain single crystals comprising [{(IPr⋅InBr3 )(Ag⋅(CH2 Cl)2 )}2 ][SbF6 ]2 (1) and two identical HSbF6 units. It is presumed that the reaction gave rise to [IPr⋅InBr3-x ][SbF6 ]x (x=1, 2, or 3) which reacted with adventitious water to give HSbF6 and [IPr⋅InBr3-x (OH)][SbF6 ]x-1 . The experiment was reproduced at 60 °C, eventually leading to the indium hydroxide [{IPr⋅In(OH)0.5 (H2 O)4.5 }2 ][SbF6 ]5 (2). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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