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Hafnium tert-butoxide | CAS Number: 2172-02-3

Catalog Number
ACM2172023
Product Name
Hafnium tert-butoxide
Structure
CAS Number
2172-02-3
Synonyms
HAFNIUM (IV) T-BUTOXIDE;HAFNIUM T-BUTOXIDE;HAFNIUM TERT-BUTOXIDE;HAFNIUM TETRA-T-BUTOXIDE;Hafnium(IV) t-butoxide (99.9%-Hf);Hafnium(IV) tert-butoxide;Hafnium tert-butoxide, 99.9% (metals basis excluding Zr), Zr;HafniuM(IV) t-butoxide (99.9%-Hf,
Molecular Weight
470.94
Molecular Formula
C16H36HfO4
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1Synthesis and structural characterization of a family of modified hafnium tert-butoxide for use as precursors to hafnia nanoparticles.

Boyle TJ1, Steele LA, Burton PD, Hoppe SM, Lockhart C, Rodriguez MA.

Inorg Chem. 2012 Nov 19;51(22):12075-92. doi: 10.1021/ic300622h. Epub 2012 Nov 6.

A series of modified, hafnium tert-butoxide ([Hf(OBu(t))4]) compounds (1-26) were crystallographically characterized, and representative species were then used to produce HfO2nanoparticles. This systematically varied family of [Hf(OR)4] compounds was developed from the reaction of [Hf(OBu(t))4] with a series of (i) Lewis basic solvents, tetrahydrofuran, pyridine, or 1-methylimidazole; (ii) simple phenols, HOC6H4(R)-2 or HOC6H3(R)2-2,6 where R = CH3, CH(CH3)2, or C(CH3)3; and (iii) complex polydentate alcohols, tetrahydrofuran methanol (H-OTHF), pyridinecarbinol (H-OPy), and tris(hydroxymethylethane) (THME-H3). Read More

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Tel:1-201-478-8534
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