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Home > Product > Material & Chemicals > Metal & Ceramic Materials > Dodecacarbonyltetrairidium

Dodecacarbonyltetrairidium | CAS Number: 11065-24-0

Catalog Number
ACM11065240
Product Name
Dodecacarbonyltetrairidium
Structure
CAS Number
11065-24-0
IUPAC Name
carbon monoxide;iridium
Synonyms
DODECACARBONYLTETRAIRIDIUM;IRIDIUM CARBONYL;TETRAIRIDIUM DODECACARBONYL;Iridiumcarbonyl,min.98%;Tetrairidium dodecarcarbonyl;Iridium carbonyl, min. 98%;Tetrairidium dodecacarbonyl 98%
Molecular Weight
1104.99
Exact Mass
1107.79000
Molecular Formula
C12Ir4O12
Melting Point
195ÂșC (dec.)(lit.)
Purity
96%
SMILES
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ir].[Ir].[Ir].[Ir]
InChIKey
XWDKRVSSHIJNJP-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
12
Safty Description
S36
Hazard Statements
Xn
Packing Group
II
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1Synthesis and characterisation of some iridium-carbonyl-fluoride complexes. Crystal structures of [IrF(CO){P(C6H4-2-CH3)3}2] and [IrF2(COD)py2][BF4].

Fawcett J1, Harding DA, Hope EG.

Dalton Trans. 2010 Jul 7;39(25):5827-32. doi: 10.1039/c0dt00066c. Epub 2010 May 25.

Two routes to iridium(III) fluorocomplexes are described. The direct reaction of tetrairidium dodecacarbonyl with elemental fluorine in aHF offers a clean, convenient, large scale route to [IrF(3)(CO)(3)]; addition of phosphines to [IrF(3)(CO)(3)] in THF affords mer-[IrF(3)(CO)L(2)] or [IrF(CO)L(2)]. Alternatively, cationic [IrF(2)(COD)L(2)](+) and [IrF(2)(CO)(2)L(2)](+) (L = phosphine, pyridine; L(2) = alpha-diimine) are accessible via the oxidation of the iridium(I) precursors with xenon difluoride.

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Tel:1-201-478-8534
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