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Home > Product > Metal Organics > Organic Tin > (Dimethylamino)trimethyltin

(Dimethylamino)trimethyltin | CAS Number: 993-50-0

Catalog Number
ACM993500
Product Name
(Dimethylamino)trimethyltin
Structure
CAS Number
993-50-0
Synonyms
Dimethylaminotrimethylstannane;Stannanamine, pentamethyl-;PENTAMETHYLSTANNANAMINE;TRIMETHYLSTANNYLDIMETHYLAMIDE;(DIMETHYLAMINO)TRIMETHYLTIN;(Dimethylamino)trimethyltin(IV), technical grade;(dimethylamino)trimethyltin(iv);N-Methyl-N-(trimethylstannyl)metha
Molecular Weight
207.89
Molecular Formula
C5H15NSn
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1Tetrylenes chelated by hybrid amido-amino ligand: derivatives of 2-[(N,N-dimethylamino)methyl]aniline.

Vaňkátová H1, Broeckaert L, De Proft F, Olejník R, Turek J, Padělková Z, Růžička A.

Inorg Chem. 2011 Oct 3;50(19):9454-64. doi: 10.1021/ic2011056. Epub 2011 Sep 8.

Reaction of 2-[(dimethylamino)methyl]aniline with butyllithium, followed by conversion with trimethylsilyl, triphenylsilyl, triphenylgermyl, trimethylstannyl, or tri-n-butylstannyl chloride, gives the corresponding substituted aniline. These compounds were further deprotonated by butyllithium and reacted with germanium, tin, and lead dichlorides, respectively, in both stoichiometric ratios 2:1 and 1:1, providing the target homo- ([2-(Me(2)NCH(2))C(6)H(4)(YR(3))N](2)M) and heteroleptic ([2-(Me(2)NCH(2))C(6)H(4)(YR(3))N]MCl) germylenes and stannylenes, where M = Ge, Sn, Y = Si, Ge, and R = Me, Ph. Read More

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