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Home > Product > Metal Organics > Organic Aluminium > Diisobutylaluminum chloride

Diisobutylaluminum chloride | CAS Number: 1779-25-5

Catalog Number
ACM1779255
Product Name
Diisobutylaluminum chloride
Structure
CAS Number
1779-25-5
Synonyms
alluminiodiisobutil-monocloruro;Aluminum,chlorodiisobutyl-;bis(isobutyl)aluminumchloride;chlorobis(2-methylpropyl)-aluminu;chlorobis(2-methylpropyl)aluminum;chlorobis(2-methylpropyl)-Aluminum;chlorodiisobutyl-aluminu;chlorodiisobutylaluminum
Molecular Weight
176.66
Molecular Formula
C8H18AlCl
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1Controlled Reduction of Tertiary Amides to the Corresponding Alcohols, Aldehydes, or Amines Using Dialkylboranes and Aminoborohydride Reagents.

Bailey CL1, Joh AY1, Hurley ZQ1, Anderson CL1, Singaram B1.

J Org Chem. 2016 May 6;81(9):3619-28. doi: 10.1021/acs.joc.6b00276. Epub 2016 Apr 12.

Dialkylboranes and aminoborohydrides are mild, selective reducing agents complementary to the commonly utilized amide reducing agents, such as lithium aluminum hydride (LiAlH4) and diisobutylaluminum hydride (DIBAL) reagents. Tertiary amides were reduced using 1 or 2 equiv of various dialkylboranes. The reduction of tertiary amides required 2 equiv of 9-borabicyclo[3.3.1]nonane (9-BBN) for complete reduction to give the corresponding tertiary amines. Read More

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Tel:1-201-478-8534
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