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Home > Product > Metal Organics > Organic Aluminium > Diisobutylaluminium hydride

Diisobutylaluminium hydride | CAS Number: 1191-15-7

Catalog Number
ACM1191157
Product Name
Diisobutylaluminium hydride
Structure
CAS Number
1191-15-7
Synonyms
DI-I-BUTYLALUMINUM HYDRIDE;DIISOBUTYLALUMINUM HYDRIDE;DIISOBUTYLALUMINIUM HYDRIDE;DIBAH;DIBAL-H;Al-Alchili;Al-Diisobutyl;Aluminum, diisobutylhydro-
Molecular Weight
142.22
Molecular Formula
C8H19Al
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1Practical synthetic strategies towards lipophilic 6-iodotetrahydroquinolines and -dihydroquinolines.

Chisholm DR1, Zhou GL1, Pohl E2, Valentine R3, Whiting A1.

Beilstein J Org Chem. 2016 Aug 16;12:1851-1862. eCollection 2016.

The synthesis of novel tetrahydroquinolines (THQ) and dihydroquinolines (DHQ) are reported using three practical, scalable synthetic approaches to access highly lipophilic analogues bearing a 6-iodo substituent, each with a different means of cyclisation. A versatile and stable quinolin-2-one intermediate was identified, which could be reduced to the corresponding THQ with borane reagents, or to the DHQ with diisobutylaluminium hydride via a novel elimination that is more favourable at higher temperatures. Read More

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Email:
Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA