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Home > Product > Precious Metal Catalyst > Dihydrogen dinitrosulfatoplatinate(II)

Dihydrogen dinitrosulfatoplatinate(II) | CAS Number: 12033-81-7

Catalog Number
ACM12033817
Product Name
Dihydrogen dinitrosulfatoplatinate(II)
Structure
CAS Number
12033-81-7
UN Number
UN3264 8 / PGIII
MDL Number
MFCD00064668
Synonyms
Hydrogen dinitrosulfatoplatinate(II)
Molecular Weight
384.17
Molecular Formula
H2Pt(NO2)2SO4
Density
1.1 g/cm3 at 20 °C(lit.)
Purity
Pt 50g/L
Appearance
light yellow liquid
Symbol
GHS05
Safty Description
Danger
Hazard Statements
H314-H318
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1Elongated Dihydrogen versus Compressed Dihydride.

Esteruelas MA1, Eguillor B, Lezáun V, Oliván M, Oñate E.

Chemistry. 2016 Dec 19. doi: 10.1002/chem.201605843. [Epub ahead of print]

Small modifications on the co-ligands of complexes containing two coordinated hydrogen atoms can determine the elongated dihydrogen versus compressed dihydride nature of these species and therefore their chemical behavior. While 2,6-diphenylpyridine favors the formation of the osmium(IV) cation [OsH2(C6H4pyPh)(PiPr3)2]+, 2-phenoxy-6-phenylpyridine, which contains an oxygen atom between the heterocycle and one of the phenyl groups, stabilizes the osmium(II) elongated dihydrogen species [Os(C6H4pyOPh)(η2-H2)(PiPr3)2]+. Read More

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