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Diethyl allylmalonate | CAS Number: 2049-80-1

Catalog Number
ACM2049801
Product Name
Diethyl allylmalonate
Structure
CAS Number
2049-80-1
Synonyms
2-propenyl-propanedioicacidiethylester;Diethyl 2-(2-propenyl)-1,3-propanedioate;Diethyl 2-(prop-2-enyl)malonate;Diethyl prop-2-enylpropanedioate;Malonic acid, allyl-, diethyl ester;Mono-allyldiethyl malonate;prop-2-enyl-propanedioicaciddiethylester;ALLYLD
Molecular Weight
200.23
Molecular Formula
C10H16O4
Purity
97%
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1Ni-Catalyzed Asymmetric Cycloisomerization of Dienes by Using TADDOL Phosphoramidites.

Schmitz C1, Leitner W2, Franciò G3.

Chemistry. 2015 Jul 20;21(30):10696-702. doi: 10.1002/chem.201500352. Epub 2015 May 26.

A library of α,α,α,α-tetraaryl-1,3-dioxolane-4,5-dimethanol (TADDOL)-based phosphoramidites has been synthesized and applied in the Ni-catalyzed cycloisomerization of different dienes. Through the systematic variation of the three structural motifs of the lead structure, that is, the amine moiety, the protecting group, and the aryl substituents, the ligand features could be optimized for the asymmetric cycloisomerization of the model substrate diethyl diallylmalonate. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA