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Diethoxymethylsilane | CAS Number: 2031-62-1

Catalog Number
ACM2031621
Product Name
Diethoxymethylsilane
Structure
CAS Number
2031-62-1
Synonyms
DIETHOXYMETHYLSILANE;METHYLDIETHOXYSILANE;diethoxymethyl-silan;Silane, diethoxymethyl-;Diethoxymethylsilane [Hydrosilylating Reagent];Diethoxymethylsilane. Methylhydrogendiethoxysilane.;Methyldiethoxysilane,97%;DiethoxyMethylsilane [Hydrosilylating Reagen
Molecular Weight
134.25
Molecular Formula
C5H14O2Si
Purity
99%
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1Copper Hydride Catalyzed Reductive Claisen Rearrangements.

Wong KC1,2, Ng E1, Wong WT1,3, Chiu P4.

Chemistry. 2016 Mar 7;22(11):3709-12. doi: 10.1002/chem.201504870. Epub 2016 Feb 4.

An efficient reductive Claisen rearrangement, catalyzed by in situ generated copper hydride and stoichiometric in diethoxymethylsilane, has been developed. Yields of up to 95 % with good to excellent diastereoselectivities were observed in this reaction. Mechanistic studies showed that the stereospecific rearrangement proceeded via a chair transition state of (E)-silyl ketene acetals as intermediates and not via the copper enolates. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Email:
Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA